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    Przestarzała nazwa cholesterolu owe cholesteryna.

    Spis treści

    1 Budowa drobin
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    2.1 Addycja do krępowania dualnego
    2.2 Utlenianie
    3 Biosynteza
    3.1 Utworzenie mewalonianu
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    3.4 Cyklizacja
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    4 Wchłanianie
    5 Krążenie
    6 Znaczenie biologiczne
    7 Cholesterol i chorób organizmu nawiedzania
    7.1 Normy zawartości we farb
    8 Ciekłokrystaliczne wtórne cholesterolu
    9 Przypisy
    10 Bibliografia
    11 Linki powierzchowne

    Budowa cząsteczek
    numeracja atomów węgla cholesterolu

    Cholesterol kwalifikujemy do steroidów. Są owe stosunki stosowne do lipoidów (cechą scalające nader odmienne substancje owej wspólnoty istnieje chuchrowata rozpuszczalność w gorzale charakteryzująca tymiż cholesterol
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    Jak w losie innych steroidów, drobina cholesterolu dysponuje 3 pierścienie sześciowęglowe
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    Oznacza się je kolejnymi literami alfabetu łacińskiego wygodnie A, B zaœ C natomiast D.
    Pierścienie sześciowęglowe, spełnione na szkicach zazwyczaj w form sześciokąta kształtnego, w rzeczywistości otrzymują konformację krzesłową.
    Niesie owe za sobą dziarskie konsekwencje. Między innymi z 12 podstawników pierścienia cykloheksanowego 6 stawianych istnieje ekwatorialnie (równikowo, w bok), 6 dodatkowych aksjalnie (3 w kupę,
    3 w rów względem akademickiej płaszczyzny pierścienia) i te właśnie cechuje potężne zjednoczenie przestrzenne.
    Wobec tego atomy węgla tworzące przylegające pierścienie spoczywają sztampowo aksjalnie, i także w położeniu stupor asumptem siebie (jedna z
    kliki przesunięta jest delikatnie do fury, druga nieszeroko w stronicę przeciwległą, paralelnie, jak w przykładzie trans-dekaliny[11]).
    Obie klik metylowe zestawione aksjalnie niejako sterczą na
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    β)[12]. Grupa hydroksylowa pochłania kładzenie ekwatorialne[12].

    algorytm molekuły

    Ta zagmatwana odrobina posiada aż 8 asymetrycznych (chiralnych) atomów węgla oznaczanych
    centrami stereogenicznymi. Są owe atomy o humoreskach 3, 8, 9,
    10, 13, 14, 17, 20. Teoretycznie korzystając z algorytmu, wedle jakiego perfekcyjna kwota izomerów wynosi 2n, dokąd n –
    wartoœć atomów chiralnych, wpływowa wypunktować, iż kompozyt taki powinien mieć 28=256 izomerów
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    enancjomerów, substancje należące do rożnych par istniałyby zaś względem siebie diastereoizomerami.

    Jednakże, jak owe przeważnie moja miejsce w przykładzie stworów plastycznych, zalęga w nich lecz jeden. Poza tym obstaje pamiętać, iż mamy do działania z cząstką
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    bycie wielu z teoretycznych izomerów[13].

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